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Radical dehalogenation

2 real reactions from the literature, on gem-dihalides and secondary alkyl iodides. Each scheme shows starting materials, conditions and products, with the yield and reference where the source reports them.

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  1. Radical dehalogenation: 7,7-dibromodispiro[2.0.2.1(3)]heptane (a gem-dihalide) with Bu3SnH, AIBN; EtOH / 40 °C gives 7-bromodispiro[2.0.2.1]heptane (the dehalogenated product).

    Radical dehalogenationEur. J. Org. Chem. 2003, 4234
  2. Radical dehalogenation: a secondary alkyl iodide with SnBu3H; AIBN gives the dehalogenated product. 87% yield.