Le Chatelier's Principle

When a system at equilibrium is disturbed, it shifts to partially counteract the change.

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Le Chatelier's Principle

Perturbation:

How will the equilibrium shift?

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Common Questions

What is Le Chatelier's Principle?

Le Chatelier's Principle states that when a system at equilibrium is disturbed, it shifts to partially counteract the disturbance and restore a new equilibrium.

How does changing concentration affect equilibrium?

Adding a reactant or removing a product shifts equilibrium toward the products (forward). Removing a reactant or adding a product shifts it toward the reactants (reverse). The system adjusts to reduce the disturbance.

How does temperature affect equilibrium?

Increasing temperature favors the endothermic direction. Decreasing temperature favors the exothermic direction. Think of heat as a reactant (endothermic) or product (exothermic).

Does a catalyst affect equilibrium position?

No. A catalyst speeds up both the forward and reverse reactions equally, so the system reaches equilibrium faster but the equilibrium position (ratio of products to reactants) does not change.